Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles

• Main Authors: Seah, Jeffrey Wee Kiong, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Chiral Phosphine; Palladium Compounds
• 在線閱讀: https://hdl.handle.net/10356/157004
• 機構: Nanyang Technological University

Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral pho...