Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles

Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles

Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral pho...

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Main Authors: Seah, Jeffrey Wee Kiong, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Chiral Phosphine
Palladium Compounds
Online Access:https://hdl.handle.net/10356/157004
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1570042023-02-28T20:05:52Z Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles Seah, Jeffrey Wee Kiong Li, Yongxin Pullarkat, Sumod A. Leung, Pak-Hing School of Physical and Mathematical Sciences Science::Chemistry Chiral Phosphine Palladium Compounds Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral phosphine-NHC palladium(II) complex with excellent overall conversion. Ministry of Education (MOE) Submitted/Accepted version This research is supported by the Ministry of Education, Singapore, under its Academic Research Fund Tier 1 (2019- T1-001-094). 2022-04-29T04:48:20Z 2022-04-29T04:48:20Z 2021 Journal Article Seah, J. W. K., Li, Y., Pullarkat, S. A. & Leung, P. (2021). Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles. Organometallics, 40(13), 2118-2122. https://dx.doi.org/10.1021/acs.organomet.1c00262 0276-7333 https://hdl.handle.net/10356/157004 10.1021/acs.organomet.1c00262 2-s2.0-85110320881 13 40 2118 2122 en 2019- T1-001-094 Organometallics This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organometallics, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.organomet.1c00262. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Chiral Phosphine
Palladium Compounds
spellingShingle Science::Chemistry
Chiral Phosphine
Palladium Compounds
Seah, Jeffrey Wee Kiong
Li, Yongxin
Pullarkat, Sumod A.
Leung, Pak-Hing
Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
description Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral phosphine-NHC palladium(II) complex with excellent overall conversion.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Seah, Jeffrey Wee Kiong
Li, Yongxin
Pullarkat, Sumod A.
Leung, Pak-Hing
format Article
author Seah, Jeffrey Wee Kiong
Li, Yongxin
Pullarkat, Sumod A.
Leung, Pak-Hing
author_sort Seah, Jeffrey Wee Kiong
title Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
title_short Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
title_full Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
title_fullStr Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
title_full_unstemmed Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles
title_sort access to a chiral phosphine-nhc palladium(ii) complex via the asymmetric hydrophosphination of achiral vinyl azoles
publishDate 2022
url https://hdl.handle.net/10356/157004
_version_ 1759855029195374592

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