Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles

• المؤلفون الرئيسيون: Seah, Jeffrey Wee Kiong, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Chiral Phosphine; Palladium Compounds
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/157004

Enantioenriched phosphine azoles were synthesized in high yields via palladium-catalyzed asymmetric hydrophosphination with excellent yields and enantioselectivities under mild reaction conditions. One of the phosphine azoles was methylated and complexed to palladium(II) cleanly to give a chiral pho...