Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)

NIR reflective materials have been actively explored towards various applications in both civilian and military fields. The complexity of various factors that influence the NIR reflection behavior has made it a challenging task to establish a clear relationship between doping elements and the reflec...

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Main Authors: Song, Yujie, Chen, Wangqiao, Lim, Xiao Ming, Hu, Xiao, Liu, Ming, Zhang, Qichun
Other Authors: School of Materials Science and Engineering
Format: Article
Language:English
Published: 2021
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Online Access:https://hdl.handle.net/10356/151251
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1512512021-06-22T03:09:13Z Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In) Song, Yujie Chen, Wangqiao Lim, Xiao Ming Hu, Xiao Liu, Ming Zhang, Qichun School of Materials Science and Engineering Research Techno Plaza Engineering::Materials NIR Reflection Tunable NIR reflective materials have been actively explored towards various applications in both civilian and military fields. The complexity of various factors that influence the NIR reflection behavior has made it a challenging task to establish a clear relationship between doping elements and the reflection performance, which should provide a general guideline to prepare new materials. In this study, for the first time, by minimizing the influence of extrinsic factors, we established the relationship between the electronic configuration in the outset orbitals of the doping metals and the NIR reflectance of doped YMn0.9M0.1O3, and found that the number of unpaired electrons in the outset 3d orbitals of the doping transition metals play an important role in tuning the NIR reflectance. We believe that our research would provide a new instruction to tailor the NIR reflection performance in the realm of inorganic materials. This work was supported by Nanyang Technological University [grant number M4062018]. 2021-06-22T03:09:12Z 2021-06-22T03:09:12Z 2019 Journal Article Song, Y., Chen, W., Lim, X. M., Hu, X., Liu, M. & Zhang, Q. (2019). Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In). Journal of Solid State Chemistry, 273, 81-84. https://dx.doi.org/10.1016/j.jssc.2019.02.040 0022-4596 https://hdl.handle.net/10356/151251 10.1016/j.jssc.2019.02.040 2-s2.0-85062214440 273 81 84 en M4062018 Journal of Solid State Chemistry © 2019 Elsevier Inc. All rights reserved.
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Engineering::Materials
NIR Reflection
Tunable
spellingShingle Engineering::Materials
NIR Reflection
Tunable
Song, Yujie
Chen, Wangqiao
Lim, Xiao Ming
Hu, Xiao
Liu, Ming
Zhang, Qichun
Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
description NIR reflective materials have been actively explored towards various applications in both civilian and military fields. The complexity of various factors that influence the NIR reflection behavior has made it a challenging task to establish a clear relationship between doping elements and the reflection performance, which should provide a general guideline to prepare new materials. In this study, for the first time, by minimizing the influence of extrinsic factors, we established the relationship between the electronic configuration in the outset orbitals of the doping metals and the NIR reflectance of doped YMn0.9M0.1O3, and found that the number of unpaired electrons in the outset 3d orbitals of the doping transition metals play an important role in tuning the NIR reflectance. We believe that our research would provide a new instruction to tailor the NIR reflection performance in the realm of inorganic materials.
author2 School of Materials Science and Engineering
author_facet School of Materials Science and Engineering
Song, Yujie
Chen, Wangqiao
Lim, Xiao Ming
Hu, Xiao
Liu, Ming
Zhang, Qichun
format Article
author Song, Yujie
Chen, Wangqiao
Lim, Xiao Ming
Hu, Xiao
Liu, Ming
Zhang, Qichun
author_sort Song, Yujie
title Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
title_short Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
title_full Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
title_fullStr Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
title_full_unstemmed Electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of YMn0.9M0.1O3 (M ¼ Cr, Mn, Fe, Co, Al, Ga and In)
title_sort electronic configuration in outset orbitals of doping elements plays as a key factor in tuning near infrared reflection of ymn0.9m0.1o3 (m ¼ cr, mn, fe, co, al, ga and in)
publishDate 2021
url https://hdl.handle.net/10356/151251
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