Cobalt-catalyzed regio- and diastereoselective formal [3 + 2] cycloaddition between cyclopropanols and allenes
A cobalt-diphosphine catalyst has been found to promote a formal [3 + 2] cycloaddition reaction between a cyclopropanol and an allene via cyclopropanol ring opening, which affords a 3-alkylidenecyclopentanol derivative with high regio- and diastereoselectivities. The reaction tolerates monosubstitut...
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Main Authors: | , , |
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Format: | Article |
Language: | English |
Published: |
2021
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/151651 |
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Institution: | Nanyang Technological University |
Language: | English |