Guanidine-copper complex catalyzed allylic borylation for the enantioconvergent synthesis of tertiary cyclic allylboronates
An enantioconvergent synthesis of chiral cyclic allylboronates from racemic allylic bromides was achieved by using a guanidine-copper catalyst. The allylboronates were obtained with high γ/α regioselectivities (up to 99:1) and enantioselectivities (up to 99 % ee), and could be further transformed in...
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| Main Authors: | , , , , , , , |
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| 格式: | Article |
| 語言: | English |
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2021
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| 在線閱讀: | https://hdl.handle.net/10356/151801 |
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