Rapid activation of diazirine biomaterials with the blue light photocatalyst

• Main Authors: Djordjevic, Ivan, Wicaksono, Gautama, Šolić, Ivan, Singh, Juhi, Kaku, Tanvi Sushil, Lim, Sierin, Ang, Elwin Wei Jian, Blancafort, Lluís, Steele, Terry W. J.
• 其他作者: School of Materials Science and Engineering
• 格式: Article
• 語言: English
• 出版: 2021
• 主題: Engineering::Materials::Biomaterials; Polycaprolactone; Diazirine; Visible Light; Cross-linking; Photocatalysis
• 在線閱讀: https://hdl.handle.net/10356/152662
• 機構: Nanyang Technological University

Carbene-based macromolecules are an emerging new stimuli-sensitive class of biomaterials that avoid the impediments of free radical polymerization but maintain a rapid liquid-to-biorubber transition. Activation of diazirine-grafted polycaprolactone polyol (CaproGlu) is limited to UVA wavelengths tha...