Synthesis of core-crosslinked star polymers via organocatalyzed living radical polymerization

• Main Authors: Zheng, Yichao, Sarkar, Jit, Niino, Hiroshi, Chatani, Shunsuke, Hsu, Shu Yao, Goto, Atsushi
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2021
• 主題: Science::Chemistry::Organic chemistry::Polymers; Polymers; Acrylic Monomers
• 在線閱讀: https://hdl.handle.net/10356/153594
• 機構: Nanyang Technological University

Core-crosslinked star polymers were prepared using organocatalyzed living radical polymerization via a “grafting-through” approach. A PBA homopolymer, an amphiphilic PMMA–PPEGA block copolymer, and a hard-soft PMMA–PBA block copolymer were synthesized as macroinitiators, where PBA is poly(butyl acry...