Catalytic access to ferrocenyl phosphines bearing both planar and central chirality – A kinetic resolution approach via catalytic asymmetric P(III)–C bond formation

• المؤلفون الرئيسيون: Abdul Sadeer, Kojima, Tadayuki, Ng, Jia Sheng, Gan, Kennard Jun Hao, Chew, Renta Jonathan, Li, Yongxin, Pullarkat, Sumod Appukuttan
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2021
• الموضوعات: Science::Chemistry; Asymmetric; Hydrophosphination
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/154139

A series of enantioenriched ferrocenyl monophosphines imbued with both central and planar chirality were obtained catalytically (80–99% ee) via the kinetic resolution of 1,2-disubstituted planar chiral ferrocenyl enone racemates. The synthetic approach utilized a chiral palladacycle to facilitate th...