Ordered array of pores on a polymer film

This project examines the arrays formed on various glass substrates using polymer solutions via the breath figure technique and were compared to find out whether a difference in number of carboxy group, weight % and substrate surface plays a part and how each variable alters the size and order of th...

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Bibliographic Details
Main Author: Fong, Yik Ling.
Other Authors: Wong, Chee Cheong
Format: Final Year Project
Language:English
Published: 2009
Subjects:
Online Access:http://hdl.handle.net/10356/15414
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Institution: Nanyang Technological University
Language: English
Description
Summary:This project examines the arrays formed on various glass substrates using polymer solutions via the breath figure technique and were compared to find out whether a difference in number of carboxy group, weight % and substrate surface plays a part and how each variable alters the size and order of the pores. Solutions of Monocarboxy – Terminated Polystyrene (PSm) of 1% to 3% in weight in Carbon Disulfide (CS2) and Dicarboxy – Terminated Polystyrene (PSd) of 1% to 3% in weight dissolved in CS2 were used in this experiment. The arrays are formed on 3 different glass surfaces; namely normal microscope glass (soda lime glass), cleaned cover slip glass (borosilicate glass) and Indium Tin Oxide (ITO) coated conductive glass. From results of the varied factors, PSm, 1wt% on normal microscopic glass gives the best monodispersed arrays with longer range order. Conductive glass gives the smallest pore size while 1wt% gives the best degree of ordering.