Metal-organic architectures driven by a multifunctional 6-aminouracil spacer : structures, noncovalent interactions, and conductivity

• Main Authors: Purkayastha, Atanu, Dhar, Sourab, Mondal, Suvra Prakash, Franconetti, Antonio, Frontera, Antonio, Ganguly, Rakesh, Kirillov, Alexander M., Misra, Tarun Kumar
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2021
• Subjects: Science::Chemistry; Sulfonated Monoazo Dyes; Coordination Polymers
• Online Access: https://hdl.handle.net/10356/154468
• Institution: Nanyang Technological University

Three new coordination polymers, [NaI(H2L)(H2O)3]n (1), {[KI(H2L)(H2O)]8·13H2O}n (2), and {[NiIINaI2(HL)2(H2O)8]·6H2O}n (3), were assembled from 1,3-dimethyl-5-(p-sulfonic-phenylazo)-6-aminouracil (H3L) as a versatile building block. Although azo-coupling reactions generally result in simple azo-com...