Axial modification of cobalt complexes on heterogeneous surface with enhanced electron transfer for carbon dioxide reduction

• Main Authors: Wang, Jiong, Huang, Xiang, Xi, Shibo, Xu, Hu, Wang, Xin
• Other Authors: School of Chemical and Biomedical Engineering
• Format: Article
• Language: English
• Published: 2021
• Subjects: Engineering::Chemical engineering; Axial Coordination; Carbon Dioxide Reduction
• Online Access: https://hdl.handle.net/10356/154566
• Institution: Nanyang Technological University

Efficient electron communication between molecular catalyst and support is critical for heterogeneous molecular electrocatalysis and yet it is often overlooked during the catalyst design. Taking CO2 electro-reduction on tetraphenylporphyrin cobalt (PCo) immobilized onto graphene as an example, we de...