Air-stable phosphine organocatalysts for the hydroarsination reaction

Readily-available triarylphosphines are explored as organocatalysts for the hydroarsination reaction. When compared to transition metal catalysis, phosphine organocatalysis greatly improved solvent compatibility of the hydroarsination of nitrostyrenes. Upon complete conversion, arsine products were...

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Main Authors: Tay, Wee Shan, Li, Yongxin, Yang, Xiang-Yuan, Pullarkat, Sumod Appukuttan, Leung, Pak-Hing
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
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Online Access:https://hdl.handle.net/10356/154630
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1546302021-12-30T02:14:07Z Air-stable phosphine organocatalysts for the hydroarsination reaction Tay, Wee Shan Li, Yongxin Yang, Xiang-Yuan Pullarkat, Sumod Appukuttan Leung, Pak-Hing School of Physical and Mathematical Sciences Division of Chemistry & Biological Chemistry Science::Chemistry Arsine Hydroarsination Readily-available triarylphosphines are explored as organocatalysts for the hydroarsination reaction. When compared to transition metal catalysis, phosphine organocatalysis greatly improved solvent compatibility of the hydroarsination of nitrostyrenes. Upon complete conversion, arsine products were isolated in up to 99% yield while up to 48% of the phosphine catalyst was still active. A mechanism was proposed and structure-activity analysis regarding catalyst activity concluded that sterically-bulkier catalysts were effective at minimizing catalyst deactivation. Nanyang Technological University W. S. T. acknowledges NTU for the award of a research scholarship. This work was supported by the Nanyang Technological University [M401110000 RG 10/19]. 2021-12-30T02:14:07Z 2021-12-30T02:14:07Z 2020 Journal Article Tay, W. S., Li, Y., Yang, X., Pullarkat, S. A. & Leung, P. (2020). Air-stable phosphine organocatalysts for the hydroarsination reaction. Journal of Organometallic Chemistry, 914, 121216-. https://dx.doi.org/10.1016/j.jorganchem.2020.121216 0022-328X https://hdl.handle.net/10356/154630 10.1016/j.jorganchem.2020.121216 2-s2.0-85081681740 914 121216 en M401110000 RG 10/19 Journal of Organometallic Chemistry © 2020 Published by Elsevier B.V. All rights reserved.
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Arsine
Hydroarsination
spellingShingle Science::Chemistry
Arsine
Hydroarsination
Tay, Wee Shan
Li, Yongxin
Yang, Xiang-Yuan
Pullarkat, Sumod Appukuttan
Leung, Pak-Hing
Air-stable phosphine organocatalysts for the hydroarsination reaction
description Readily-available triarylphosphines are explored as organocatalysts for the hydroarsination reaction. When compared to transition metal catalysis, phosphine organocatalysis greatly improved solvent compatibility of the hydroarsination of nitrostyrenes. Upon complete conversion, arsine products were isolated in up to 99% yield while up to 48% of the phosphine catalyst was still active. A mechanism was proposed and structure-activity analysis regarding catalyst activity concluded that sterically-bulkier catalysts were effective at minimizing catalyst deactivation.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Tay, Wee Shan
Li, Yongxin
Yang, Xiang-Yuan
Pullarkat, Sumod Appukuttan
Leung, Pak-Hing
format Article
author Tay, Wee Shan
Li, Yongxin
Yang, Xiang-Yuan
Pullarkat, Sumod Appukuttan
Leung, Pak-Hing
author_sort Tay, Wee Shan
title Air-stable phosphine organocatalysts for the hydroarsination reaction
title_short Air-stable phosphine organocatalysts for the hydroarsination reaction
title_full Air-stable phosphine organocatalysts for the hydroarsination reaction
title_fullStr Air-stable phosphine organocatalysts for the hydroarsination reaction
title_full_unstemmed Air-stable phosphine organocatalysts for the hydroarsination reaction
title_sort air-stable phosphine organocatalysts for the hydroarsination reaction
publishDate 2021
url https://hdl.handle.net/10356/154630
_version_ 1722355390909251584