Anti-Markovnikov hydrofunctionalization of alkenes : use of a benzyl group as a traceless redox-active hydrogen donor

• المؤلفون الرئيسيون: Lonca, Geoffroy Hervé, Ong, Derek Yiren, Tran, Thi Mai Huong, Tejo, Ciputra, Chiba, Shunsuke, Gagosz, Fabien
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Alkene Functionalization; Azidation
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/154855

A protocol for the anti-Markovnikov hydrofunctionalization of alkenes has been developed by the use of a benzyl group as a traceless redox-active hydrogen donor. Under copper catalysis and in the presence of CF3 - or N3 -containing hypervalent iodine reagents, a series of homoallylic alcohol derivat...