Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating
Outdoor environment including moisture, dust, UV, oxygen and thermal stress (repeated heating-cooling) is devastating to perovskite solar cells (PSCs). Here, we demonstrate a new strategy to make fully printed PSCs stable with maximum power output in outdoor environment by coating them with a porous...
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sg-ntu-dr.10356-1549082022-01-14T04:41:30Z Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating Luo, Jianqiang Yang, Hong Bin Zhuang, Mingxiang Liu, Shujuan Wang, Liang Liu, Bin School of Chemical and Biomedical Engineering Engineering::Chemical engineering Perovskite Solar Cells Inorganic Encapsulation Outdoor environment including moisture, dust, UV, oxygen and thermal stress (repeated heating-cooling) is devastating to perovskite solar cells (PSCs). Here, we demonstrate a new strategy to make fully printed PSCs stable with maximum power output in outdoor environment by coating them with a porous hydrophobic inorganic layer. After coating, the PSCs can maintain superior stability of more than 150 days of outdoor storage, 240 h of continuous operation at the maximum power output point in ambient air with relative humidity as high as ~80%, and stable operation for more than 10 h under raining condition. ANSYS simulation shows that the thin and porous nature of the inorganic coating layer offers much better heat dissipation than conventional encapsulation methods using glasses attached by photocurable epoxy. A similar thermal expansion coefficient of the inorganic encapsulation material with the solar cell substrate can also prevent it from cracking after repeated heating-cooling cycles. All of these merits resulted from our encapsulation method endow the perovskite solar cells with the real outdoor working capability. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University The authors acknowledge A∗Star (M4070178.120), Nanyang Technological University (M4080977.120), Ministry of Education of Singapore (M4011021.120), National Natural Foundation of China (Grant No. 21667002); Foundation of State Key Laboratory of Nuclear Resources and Environment, East China University of Technology (Grant No. NRE1602). 2022-01-14T04:41:30Z 2022-01-14T04:41:30Z 2020 Journal Article Luo, J., Yang, H. B., Zhuang, M., Liu, S., Wang, L. & Liu, B. (2020). Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating. Journal of Energy Chemistry, 50, 332-338. https://dx.doi.org/10.1016/j.jechem.2020.03.082 2095-4956 https://hdl.handle.net/10356/154908 10.1016/j.jechem.2020.03.082 2-s2.0-85083391877 50 332 338 en M4070178.120 M4080977.120 M4011021.120 Journal of Energy Chemistry © 2020 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
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Engineering::Chemical engineering Perovskite Solar Cells Inorganic Encapsulation Luo, Jianqiang Yang, Hong Bin Zhuang, Mingxiang Liu, Shujuan Wang, Liang Liu, Bin Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
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Outdoor environment including moisture, dust, UV, oxygen and thermal stress (repeated heating-cooling) is devastating to perovskite solar cells (PSCs). Here, we demonstrate a new strategy to make fully printed PSCs stable with maximum power output in outdoor environment by coating them with a porous hydrophobic inorganic layer. After coating, the PSCs can maintain superior stability of more than 150 days of outdoor storage, 240 h of continuous operation at the maximum power output point in ambient air with relative humidity as high as ~80%, and stable operation for more than 10 h under raining condition. ANSYS simulation shows that the thin and porous nature of the inorganic coating layer offers much better heat dissipation than conventional encapsulation methods using glasses attached by photocurable epoxy. A similar thermal expansion coefficient of the inorganic encapsulation material with the solar cell substrate can also prevent it from cracking after repeated heating-cooling cycles. All of these merits resulted from our encapsulation method endow the perovskite solar cells with the real outdoor working capability. |
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School of Chemical and Biomedical Engineering |
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School of Chemical and Biomedical Engineering Luo, Jianqiang Yang, Hong Bin Zhuang, Mingxiang Liu, Shujuan Wang, Liang Liu, Bin |
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Article |
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Luo, Jianqiang Yang, Hong Bin Zhuang, Mingxiang Liu, Shujuan Wang, Liang Liu, Bin |
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Luo, Jianqiang |
title |
Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
title_short |
Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
title_full |
Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
title_fullStr |
Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
title_full_unstemmed |
Making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
title_sort |
making fully printed perovskite solar cells stable outdoor with inorganic superhydrophobic coating |
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2022 |
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https://hdl.handle.net/10356/154908 |
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1722355294459133952 |