Synthesis and reactivity of bioinspired superoxocopper(II) complexes

• المؤلف الرئيسي: Laxmi, Shoba
• مؤلفون آخرون: Mihaiela Stuparu
• التنسيق: Thesis-Master by Research
• اللغة: English
• منشور في: Nanyang Technological University 2022
• الموضوعات: Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/154960
• المؤسسة: Nanyang Technological University

End-on superoxocopper(II) are evidenced to be active oxidants in a number of copper-containing oxygenase enzymes which are responsible for catalysing the stereoselective oxidation of moderate strength C─H bonds at ambient temperatures. Presently, there are over twenty synthetic biomimetic end-on sup...