Synthesis & complexation of tripodal tris (1,2,3-triazol-5-ylidene) mesoionic carbene ligands

• Main Author: Laxmi, Shoba
• Other Authors: Jason England
• Format: Final Year Project
• Language: English
• Published: 2018
• Subjects: DRNTU::Science::Chemistry::Inorganic chemistry::Metals; DRNTU::Science::Chemistry::Inorganic chemistry::Synthesis
• Online Access: http://hdl.handle.net/10356/76187
• Institution: Nanyang Technological University

Herein, the synthesis and coordination of a new 1,2,3-triazol-5-ylidene ligand system using cobalt salts to form an imido cobalt complex. 1,2,3-triazol-5-ylidenes are a special class of mesoionic carbenes (MICs) synthesised from triazoles, which are conveniently obtained through [2+3] “click” cycloa...