Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes

Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes

Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well a...

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Main Authors: Teng, Shenghan, Jiao, Zhiwei, Chi, Robin Yonggui, Zhou, Steve Jianrong
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Allenes
Asymmetric Catalysis
Online Access:https://hdl.handle.net/10356/155085
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1550852023-02-28T19:52:23Z Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes Teng, Shenghan Jiao, Zhiwei Chi, Robin Yonggui Zhou, Steve Jianrong School of Physical and Mathematical Sciences Science::Chemistry Allenes Asymmetric Catalysis Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines. Agency for Science, Technology and Research (A*STAR) Economic Development Board (EDB) Accepted version We acknowledge financial support from Peking University Shenzhen Graduate School, Shenzhen Bay Laboratory (21230011-Scripps), Nanyang Technological University, the GSK-EDB Trust Fund (2017 GSK-EDB Green and Sustainable Manufacturing Award), and A*STAR Science and Engineering Research Council (AMEIRGA1783c0010).. 2022-02-08T08:48:03Z 2022-02-08T08:48:03Z 2020 Journal Article Teng, S., Jiao, Z., Chi, R. Y. & Zhou, S. J. (2020). Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes. Angewandte Chemie International Edition, 59(6), 2246-2250. https://dx.doi.org/10.1002/anie.201911961 1433-7851 https://hdl.handle.net/10356/155085 10.1002/anie.201911961 31691440 2-s2.0-85077078795 6 59 2246 2250 en AME IRG A1783c0010 Angewandte Chemie International Edition This is the peer reviewed version of the following article: Teng, S., Jiao, Z., Chi, R. Y. & Zhou, S. J. (2020). Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes. Angewandte Chemie International Edition, 59(6), 2246-2250, which has been published in final form at https://doi.org/10.1002/anie.201911961. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Allenes
Asymmetric Catalysis
spellingShingle Science::Chemistry
Allenes
Asymmetric Catalysis
Teng, Shenghan
Jiao, Zhiwei
Chi, Robin Yonggui
Zhou, Steve Jianrong
Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
description Palladium-catalyzed three-component carboetherification of cyclic alkenes proceeded to give trans adducts exclusively with excellent enantioselectivity through a Wacker-type pathway. The reaction is also applicable to other oxygen nucleophiles, such as water, phenols, and carboxylic acids, as well as some electron-poor aryl amines.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Teng, Shenghan
Jiao, Zhiwei
Chi, Robin Yonggui
Zhou, Steve Jianrong
format Article
author Teng, Shenghan
Jiao, Zhiwei
Chi, Robin Yonggui
Zhou, Steve Jianrong
author_sort Teng, Shenghan
title Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
title_short Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
title_full Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
title_fullStr Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
title_full_unstemmed Asymmetric Wacker-type oxyallenylation and azaallenylation of cyclic alkenes
title_sort asymmetric wacker-type oxyallenylation and azaallenylation of cyclic alkenes
publishDate 2022
url https://hdl.handle.net/10356/155085
_version_ 1759854097304911872

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