Chemoselective synthesis and evaluation of β-oxovinylarsines as an arsenic synthetic precursor

• Main Authors: Tay, Wee Shan, Li, Yongxin, Lu, Yunpeng, Pullarkat, Sumod A., Leung, Pak-Hing
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Catalysts; Isomers
• 在線閱讀: https://hdl.handle.net/10356/155189

β-Oxovinylarsines are introduced as a stable and highly functionalized bench-top arsenic precursor. Stereoselective syntheses furnished geometrically pure cis- A nd trans-isomers from the same ynone under different conditions. The organic Michael acceptor backbone allowed β-oxovinylarsines to be eas...