Chemoselective synthesis and evaluation of β-oxovinylarsines as an arsenic synthetic precursor

• المؤلفون الرئيسيون: Tay, Wee Shan, Li, Yongxin, Lu, Yunpeng, Pullarkat, Sumod A., Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Catalysts; Isomers
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/155189
• المؤسسة: Nanyang Technological University

β-Oxovinylarsines are introduced as a stable and highly functionalized bench-top arsenic precursor. Stereoselective syntheses furnished geometrically pure cis- A nd trans-isomers from the same ynone under different conditions. The organic Michael acceptor backbone allowed β-oxovinylarsines to be eas...