Intermolecular reductive heck reaction of unactivated aliphatic alkenes with organohalides

• Main Authors: Zheng, Kewang, Xiao, Guanlin, Guo, Tao, Ding, Yalan, Wang, Chengdong, Loh, Teck-Peng, Wu, Xiaojin
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Hydrocarbons; Inorganic compounds
• 在線閱讀: https://hdl.handle.net/10356/155334

A general intermolecular reductive Heck reaction of organohalides with both terminal and internal unactivated aliphatic alkenes has been first realized in high yield with complete anti-Markovnikov selectivity. The challenging vinyl bromides, aryl chlorides, and polysubstituted internal alkenes were...