Intermolecular reductive heck reaction of unactivated aliphatic alkenes with organohalides

• المؤلفون الرئيسيون: Zheng, Kewang, Xiao, Guanlin, Guo, Tao, Ding, Yalan, Wang, Chengdong, Loh, Teck-Peng, Wu, Xiaojin
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Hydrocarbons; Inorganic compounds
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/155334
• المؤسسة: Nanyang Technological University

A general intermolecular reductive Heck reaction of organohalides with both terminal and internal unactivated aliphatic alkenes has been first realized in high yield with complete anti-Markovnikov selectivity. The challenging vinyl bromides, aryl chlorides, and polysubstituted internal alkenes were...