A highly strained Al-Al σ-bond in dianionic aluminum analog of oxirane for molecule activation

• المؤلفون الرئيسيون: Koshino, Kota, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Aluminum Alloys; Spectroscopic Analysis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/159347
• المؤسسة: Nanyang Technological University

Since aluminum is the most electropositive element among the p-block elements, the construction of molecules bearing a dianionic Al-Al σ-bond is inherently highly challenging. Herein, we report the first synthesis of a dianionic dialane(6) 2 based on the Al2O three-membered ring scaffold, namely, an...