Intramolecular alkene-alkene coupling via Rh(III)-catalyzed alkenyl sp² C-H functionalization: divergent pathways to indene or α-naphthol derivatives

Intramolecular alkene-alkene coupling via Rh(III)-catalyzed alkenyl sp² C-H functionalization: divergent pathways to indene or α-naphthol derivatives

Highly selective synthesis of either indene or 1-naphthol derivatives through intramolecular alkene-alkene cross-coupling is reported. The reaction works with different alkene pairs that couple to give the corresponding products in good to satisfactory yields. The indene products of our reaction als...

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Bibliographic Details
Main Authors: Maraswami, Manikantha, Diggins, Thomas, Goh, Jeffrey, Tio, Raymond, Ong, Renee Wan Qing, Hirao, Hajime, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Alkene
Indene
Online Access:https://hdl.handle.net/10356/159960
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Institution: Nanyang Technological University
Language: English
Description
Summary:Highly selective synthesis of either indene or 1-naphthol derivatives through intramolecular alkene-alkene cross-coupling is reported. The reaction works with different alkene pairs that couple to give the corresponding products in good to satisfactory yields. The indene products of our reaction also allow further derivatization. The reaction pathway is dependent on alkene functionalities.

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