Intramolecular alkene-alkene coupling via Rh(III)-catalyzed alkenyl sp² C-H functionalization: divergent pathways to indene or α-naphthol derivatives

• Main Authors: Maraswami, Manikantha, Diggins, Thomas, Goh, Jeffrey, Tio, Raymond, Ong, Renee Wan Qing, Hirao, Hajime, Loh, Teck-Peng
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Alkene; Indene
• 在線閱讀: https://hdl.handle.net/10356/159960
• 機構: Nanyang Technological University

Highly selective synthesis of either indene or 1-naphthol derivatives through intramolecular alkene-alkene cross-coupling is reported. The reaction works with different alkene pairs that couple to give the corresponding products in good to satisfactory yields. The indene products of our reaction als...