Diboron-carbene complexes derived from a geminal dianion

• Main Authors: Fan, Jun, Yang, Ming-Chung, Hooper, Thomas J. N., Su, Ming-Der, So, Cheuk-Wai
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Science::Chemistry; Electronic Structure; Toluene
• 在線閱讀: https://hdl.handle.net/10356/160147

The reaction of the bis(thiophosphinoyl) geminal dianion [C(PPh2S)2]2- with B2Br4(SMe2)2 in toluene afforded the diboron-carbene complex [(SPh2P)2CB]2 (2). The lability of the boron-carbene bond was found in the reaction of the sterically hindered thiophosphinoyl iminophosphoranyl geminal dianion [C...