Synthesis and properties of bis-corannulenes

• المؤلفون الرئيسيون: Halilovic, Dzeneta, Rajeshkumar, Venkatachalam, Stuparu, Mihaiela Corina
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Bis-Corannulenes; Bicorannulene System
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/160360

Corannulenecarbaldehyde and corannulenylmethyl triphenylphosphonium bromide are combined through the Wittig olefination reaction to furnish dicorannulenylethene with 70% yield. A subsequent oxidative photocyclization leads to annulation of the corannulene nuclei to produce a C42H18 nanographene stru...