High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications

The basement of eastern Mexico comprises Grenvillian-age granulite-facies metamorphic rocks. The Oaxacan Complex represents the largest outcrop belt of this basement in Mexico. In this work, southwestern Oaxacan Complex garnets are studied from a petrographical, geochemical, and geothermobarometrica...

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Main Authors: Culí, Laura, Solé, Jesús, Campeny, Marc, Oalmann, Jeffry
Other Authors: Earth Observatory of Singapore
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Language:English
Published: 2022
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Online Access:https://hdl.handle.net/10356/160797
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spelling sg-ntu-dr.10356-1607972022-08-06T20:11:30Z High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications Culí, Laura Solé, Jesús Campeny, Marc Oalmann, Jeffry Earth Observatory of Singapore Science::Geology Grenvillian Orogeny Oaxacan Complex The basement of eastern Mexico comprises Grenvillian-age granulite-facies metamorphic rocks. The Oaxacan Complex represents the largest outcrop belt of this basement in Mexico. In this work, southwestern Oaxacan Complex garnets are studied from a petrographical, geochemical, and geothermobarometrical perspective for the first time. The studied garnets display different grain sizes nucleated in a polyphase evolution. The almandine end member proportion is similar in all of the studied lithotypes. The highest pyrope concentrations are found in Qz Fsp paragenesis and ultramafic rocks and the lowest pyrope concentrations are found in amphibolite. The highest grossular and spessartine concentrations are found in the amphibolite lithotype. Southwestern Oaxacan Complex garnets from paraderivate samples are more enriched in Rb, Ba, Pb, Ni, and Zn than those from orthoderivate samples enriched in Ti and V. This fact is related to the nature of the protoliths and the mineral phases that fractionate the same minor and trace elements. Garnets from para-and orthoderivate samples display 0.02–1.1 Eu/Eu* anomalies. This fact indicates that almost all of the garnets formed while the plagioclase was stable, and it does not rule out the interpretation that some garnets were peritectic. The pressure obtained using a Grt-Opx-Pl-Qz geobarometer in the southwestern Oaxacan Complex is higher than the pressure obtained in the northern part of the Complex, and it is consistent with the pressure obtained in the Grenvillian-age granulites of the Novillo Gneiss from northeastern Mexico. Geothermobarometric studies reveal different P-T features at the study site, so different structural levels of the orogen are inferred. Published version This research was funded by CONACYT grant number 240226 and DGAPA-UNAM grant number IN111917. 2022-08-03T01:46:20Z 2022-08-03T01:46:20Z 2021 Journal Article Culí, L., Solé, J., Campeny, M. & Oalmann, J. (2021). High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications. Minerals, 11(8), 805-. https://dx.doi.org/10.3390/min11080805 2075-163X https://hdl.handle.net/10356/160797 10.3390/min11080805 2-s2.0-85111086165 8 11 805 en Minerals © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https:// creativecommons.org/licenses/by/ 4.0/). application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Geology
Grenvillian Orogeny
Oaxacan Complex
spellingShingle Science::Geology
Grenvillian Orogeny
Oaxacan Complex
Culí, Laura
Solé, Jesús
Campeny, Marc
Oalmann, Jeffry
High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
description The basement of eastern Mexico comprises Grenvillian-age granulite-facies metamorphic rocks. The Oaxacan Complex represents the largest outcrop belt of this basement in Mexico. In this work, southwestern Oaxacan Complex garnets are studied from a petrographical, geochemical, and geothermobarometrical perspective for the first time. The studied garnets display different grain sizes nucleated in a polyphase evolution. The almandine end member proportion is similar in all of the studied lithotypes. The highest pyrope concentrations are found in Qz Fsp paragenesis and ultramafic rocks and the lowest pyrope concentrations are found in amphibolite. The highest grossular and spessartine concentrations are found in the amphibolite lithotype. Southwestern Oaxacan Complex garnets from paraderivate samples are more enriched in Rb, Ba, Pb, Ni, and Zn than those from orthoderivate samples enriched in Ti and V. This fact is related to the nature of the protoliths and the mineral phases that fractionate the same minor and trace elements. Garnets from para-and orthoderivate samples display 0.02–1.1 Eu/Eu* anomalies. This fact indicates that almost all of the garnets formed while the plagioclase was stable, and it does not rule out the interpretation that some garnets were peritectic. The pressure obtained using a Grt-Opx-Pl-Qz geobarometer in the southwestern Oaxacan Complex is higher than the pressure obtained in the northern part of the Complex, and it is consistent with the pressure obtained in the Grenvillian-age granulites of the Novillo Gneiss from northeastern Mexico. Geothermobarometric studies reveal different P-T features at the study site, so different structural levels of the orogen are inferred.
author2 Earth Observatory of Singapore
author_facet Earth Observatory of Singapore
Culí, Laura
Solé, Jesús
Campeny, Marc
Oalmann, Jeffry
format Article
author Culí, Laura
Solé, Jesús
Campeny, Marc
Oalmann, Jeffry
author_sort Culí, Laura
title High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
title_short High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
title_full High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
title_fullStr High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
title_full_unstemmed High-temperature metamorphic garnets from Grenvillian granulites of southwestern Oaxacan Complex (Southern Mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
title_sort high-temperature metamorphic garnets from grenvillian granulites of southwestern oaxacan complex (southern mexico): petrology, geochemistry, geothermobarometry, and tectonic implications
publishDate 2022
url https://hdl.handle.net/10356/160797
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