Efficient nitrate synthesis via ambient nitrogen oxidation with Ru-doped TiO₂/RuO₂ electrocatalysts

• Main Authors: Kuang, Min, Wang, Yu, Fang, Wei, Tan, Huiteng, Chen, Mengxin, Yao, Jiandong, Liu, Chuntai, Xu, Jianwei, Zhou, Kun, Yan, Qingyu
• 其他作者: School of Materials Science and Engineering
• 格式: Article
• 語言: English
• 出版: 2022
• 主題: Engineering::Materials; Ambient Nitrate Synthesis; Composite Electrocatalysts
• 在線閱讀: https://hdl.handle.net/10356/161092
• 機構: Nanyang Technological University

A facile pathway of the electrocatalytic nitrogen oxidation reaction (NOR) to nitrate is proposed, and Ru-doped TiO2 /RuO2 (abbreviated as Ru/TiO2 ) as a proof-of-concept catalyst is employed accordingly. Density functional theory (DFT) calculations suggest that Ruδ + can function as the main active...