Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines
The dianionic cluster [Os10(µ6-C)(CO)24]2− reacts with excess SbX3 or p-tolylSbX2 to form the monoanionic clusters [Os10{µ4-Sb(p-tolyl)nX2-n}(µ6-C)(CO)24]− (n = 0; X = Cl, I; n = 1, X = Cl) via insertion into an Os–Os bond. Further insertion into an Os–Os bond occurs when they are reacted further wi...
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sg-ntu-dr.10356-1611302022-08-16T07:07:25Z Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Samanta, Samya Leong, Weng Kee School of Physical and Mathematical Sciences Science::Chemistry Osmium Antimony The dianionic cluster [Os10(µ6-C)(CO)24]2− reacts with excess SbX3 or p-tolylSbX2 to form the monoanionic clusters [Os10{µ4-Sb(p-tolyl)nX2-n}(µ6-C)(CO)24]− (n = 0; X = Cl, I; n = 1, X = Cl) via insertion into an Os–Os bond. Further insertion into an Os–Os bond occurs when they are reacted further with excess iodine. The chemistry and structure of these clusters can be understood in terms of the isolobal analogy between [Sb(p-tolyl)nX2-n)]+ and I+. Ministry of Education (MOE) Nanyang Technological University This work was supported by Nanyang Technological University and the Ministry of Education (Research Grant No. RG15/17). 2022-08-16T07:07:24Z 2022-08-16T07:07:24Z 2021 Journal Article Barik, C. K., Ganguly, R., Li, Y., Samanta, S. & Leong, W. K. (2021). Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines. Journal of Cluster Science, 32(4), 929-935. https://dx.doi.org/10.1007/s10876-020-01857-w 1040-7278 https://hdl.handle.net/10356/161130 10.1007/s10876-020-01857-w 2-s2.0-85089145927 4 32 929 935 en RG15/17 Journal of Cluster Science © 2020 Springer Science+Business Media, LLC, part of Springer Nature. All rights reserved. |
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Science::Chemistry Osmium Antimony Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Samanta, Samya Leong, Weng Kee Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| description |
The dianionic cluster [Os10(µ6-C)(CO)24]2− reacts with excess SbX3 or p-tolylSbX2 to form the monoanionic clusters [Os10{µ4-Sb(p-tolyl)nX2-n}(µ6-C)(CO)24]− (n = 0; X = Cl, I; n = 1, X = Cl) via insertion into an Os–Os bond. Further insertion into an Os–Os bond occurs when they are reacted further with excess iodine. The chemistry and structure of these clusters can be understood in terms of the isolobal analogy between [Sb(p-tolyl)nX2-n)]+ and I+. |
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School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Samanta, Samya Leong, Weng Kee |
| format |
Article |
| author |
Barik, Chandan Kr Ganguly, Rakesh Li, Yongxin Samanta, Samya Leong, Weng Kee |
| author_sort |
Barik, Chandan Kr |
| title |
Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| title_short |
Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| title_full |
Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| title_fullStr |
Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| title_full_unstemmed |
Reaction of the decaosmium carbido cluster [Os₁₀(µ₆-C)(CO)₂₄]²⁻ with halostibines |
| title_sort |
reaction of the decaosmium carbido cluster [os₁₀(µ₆-c)(co)₂₄]²⁻ with halostibines |
| publishDate |
2022 |
| url |
https://hdl.handle.net/10356/161130 |
| _version_ |
1743119611973337088 |