A neutral and aromatic boron-rich inorganic benzene

A neutral and aromatic boron-rich inorganic benzene

A neutral 1,4-diaza-2,3,5,6-tetraborinine derivative (3) featuring a 6π ring system has been synthesized and structurally characterized. The prospective aromatic nature of 3 was assessed by single-crystal X-ray analysis, NMR, and UV/Vis absorption spectroscopy as well as computational studies. Furth...

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Main Authors: Ota, Kei, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Aromaticity
Benzene
Online Access:https://hdl.handle.net/10356/161180
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1611802023-02-28T20:10:49Z A neutral and aromatic boron-rich inorganic benzene Ota, Kei Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry Aromaticity Benzene A neutral 1,4-diaza-2,3,5,6-tetraborinine derivative (3) featuring a 6π ring system has been synthesized and structurally characterized. The prospective aromatic nature of 3 was assessed by single-crystal X-ray analysis, NMR, and UV/Vis absorption spectroscopy as well as computational studies. Furthermore, preliminary reactivity investigations showed that 3 does not only react with diphenyl acetylene but also readily captures CO2 in a [4+2] cycloaddition under ambient conditions. Ministry of Education (MOE) Nanyang Technological University Submitted/Accepted version This work was financially supported by Nanyang Technolog-ical University (NTU), Singapore, and the Singapore Ministryof Education (MOE2018-T2-2-048(S)) for R.K. 2022-08-17T08:38:54Z 2022-08-17T08:38:54Z 2020 Journal Article Ota, K. & Kinjo, R. (2020). A neutral and aromatic boron-rich inorganic benzene. Angewandte Chemie International Edition, 59(16), 6572-6575. https://dx.doi.org/10.1002/anie.201915790 1433-7851 https://hdl.handle.net/10356/161180 10.1002/anie.201915790 31989724 2-s2.0-85080051861 16 59 6572 6575 en MOE2018-T2-2-048(S) Angewandte Chemie International Edition This is the peer reviewed version of the following article: Ota, K. & Kinjo, R. (2020). A neutral and aromatic boron-rich inorganic benzene. Angewandte Chemie International Edition, 59(16), 6572-6575, which has been published in final form at https://doi.org/10.1002/anie.201915790. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Aromaticity
Benzene
spellingShingle Science::Chemistry
Aromaticity
Benzene
Ota, Kei
Kinjo, Rei
A neutral and aromatic boron-rich inorganic benzene
description A neutral 1,4-diaza-2,3,5,6-tetraborinine derivative (3) featuring a 6π ring system has been synthesized and structurally characterized. The prospective aromatic nature of 3 was assessed by single-crystal X-ray analysis, NMR, and UV/Vis absorption spectroscopy as well as computational studies. Furthermore, preliminary reactivity investigations showed that 3 does not only react with diphenyl acetylene but also readily captures CO2 in a [4+2] cycloaddition under ambient conditions.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ota, Kei
Kinjo, Rei
format Article
author Ota, Kei
Kinjo, Rei
author_sort Ota, Kei
title A neutral and aromatic boron-rich inorganic benzene
title_short A neutral and aromatic boron-rich inorganic benzene
title_full A neutral and aromatic boron-rich inorganic benzene
title_fullStr A neutral and aromatic boron-rich inorganic benzene
title_full_unstemmed A neutral and aromatic boron-rich inorganic benzene
title_sort neutral and aromatic boron-rich inorganic benzene
publishDate 2022
url https://hdl.handle.net/10356/161180
_version_ 1759854257986600960

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