Zero-valent species of group 13–15 elements

This perspective describes the development of zero-valent species En(0) of group 13–15 elements. Computational studies providing reinterpretation of bonding involved in well-known molecules, such as carbodiphosphorane, have opened up the area. Employment of Lewis bases to form donor-acceptor interac...

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Main Authors: Ota, Kei, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
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Online Access:https://hdl.handle.net/10356/161185
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1611852023-02-28T20:10:50Z Zero-valent species of group 13–15 elements Ota, Kei Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry Infrared-Spectra C-4 Cumulene This perspective describes the development of zero-valent species En(0) of group 13–15 elements. Computational studies providing reinterpretation of bonding involved in well-known molecules, such as carbodiphosphorane, have opened up the area. Employment of Lewis bases to form donor-acceptor interactions with the elemental fragments in the zero oxidation state is the key to stabilizing such species. Because of the diversity of Lewis bases available, En(0) derivatives with a variety of bonding and structural motifs are isolable. The monoatomic E1(0) species of group 13 and 15 elements, middle-size En(0) clusters (n = 4–6) of group 13 and 14 elements, and the heavier group 13 cousins have been much less explored. The end of the article outlines one of the potential future directions of zero-valent main-group chemistry, which is an exploration of the allotrope chemistry relevant to materials science. Ministry of Education (MOE) Submitted/Accepted version This work was supported by the Singapore Ministry of Education (MOE2018-T2-2- 048 (S)). 2022-08-18T05:02:53Z 2022-08-18T05:02:53Z 2022 Journal Article Ota, K. & Kinjo, R. (2022). Zero-valent species of group 13–15 elements. Chem, 8(2), 340-350. https://dx.doi.org/10.1016/j.chempr.2022.01.010 2451-9294 https://hdl.handle.net/10356/161185 10.1016/j.chempr.2022.01.010 2-s2.0-85124133648 2 8 340 350 en MOE2018-T2-2- 048 (S) Chem © 2022 Elsevier Inc. All rights reserved. This paper was published in Chem and is made available with permission of Elsevier Inc. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Infrared-Spectra
C-4 Cumulene
spellingShingle Science::Chemistry
Infrared-Spectra
C-4 Cumulene
Ota, Kei
Kinjo, Rei
Zero-valent species of group 13–15 elements
description This perspective describes the development of zero-valent species En(0) of group 13–15 elements. Computational studies providing reinterpretation of bonding involved in well-known molecules, such as carbodiphosphorane, have opened up the area. Employment of Lewis bases to form donor-acceptor interactions with the elemental fragments in the zero oxidation state is the key to stabilizing such species. Because of the diversity of Lewis bases available, En(0) derivatives with a variety of bonding and structural motifs are isolable. The monoatomic E1(0) species of group 13 and 15 elements, middle-size En(0) clusters (n = 4–6) of group 13 and 14 elements, and the heavier group 13 cousins have been much less explored. The end of the article outlines one of the potential future directions of zero-valent main-group chemistry, which is an exploration of the allotrope chemistry relevant to materials science.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Ota, Kei
Kinjo, Rei
format Article
author Ota, Kei
Kinjo, Rei
author_sort Ota, Kei
title Zero-valent species of group 13–15 elements
title_short Zero-valent species of group 13–15 elements
title_full Zero-valent species of group 13–15 elements
title_fullStr Zero-valent species of group 13–15 elements
title_full_unstemmed Zero-valent species of group 13–15 elements
title_sort zero-valent species of group 13–15 elements
publishDate 2022
url https://hdl.handle.net/10356/161185
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