Crystalline boragermenes

Boragermene 3 featuring a double bond between the Ge and dicoordinate B atoms has been synthesized for the first time by reacting the cyclic (alkyl)(boryl)germylene-PMe3 adduct 1 with Cl2 BN(SiMe3 )2 followed by reductive dehalogenation with KC8 . Addition of a Lewis base (Me NHC) to 3 leads to the...

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Bibliographic Details
Main Authors: Rao, Bin, Kinjo, Rei
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/161186
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Institution: Nanyang Technological University
Language: English