Synthesis of α-tertiary amines by polysulfide anions photocatalysis via single-electron transfer and hydrogen atom transfer in relays

• المؤلفون الرئيسيون: Li, Haoyu, Chiba, Shunsuke
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Polysulfide Anions; Radicals
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/161648
• المؤسسة: Nanyang Technological University

α,α,α-Trisubstituted amines (α-tertiary amines) are an important class of compounds in drug discovery programs. Herein, we report a photocatalytic method to synthesize α-tertiary amines using polysulfide anions as photocatalysts that facilitate single-electron transfer (SET) and hydrogen atom transf...