Synthesis of a π-extended azacorannulenophane enabled by strain-induced 1,3-dipolar cycloaddition

Synthesis of a π-extended azacorannulenophane enabled by strain-induced 1,3-dipolar cycloaddition

The first example of a cyclophane bearing a nitrogen-containing buckybowl was synthesized via sequential 1,3-dipolar cycloaddition and palladium-catalyzed intramolecular cyclization. The key to the successful synthesis is the strain-induced 1,3-dipolar cycloaddition of a polycyclic aromatic azomethi...

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Bibliographic Details
Main Authors: Zhang, Xinjiang, Mackinnon, Marc R., Bodwell, Graham J., Ito, Shingo
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Azacorannulenes
Cycloadditions
Online Access:https://hdl.handle.net/10356/161664
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/161664

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