How to install Boron into aromatic scaffolds: chemistry of diazadiborinines
The concept of aromaticity has been of paramount significance in myriad fields of chemistry. To modulate the intrinsic electronic nature of aromatic molecules, partial incorporation of heteroatoms into the benzene scaffold represents a useful strategy in modern inorganic chemistry. This account pres...
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sg-ntu-dr.10356-1618022022-09-20T06:37:13Z How to install Boron into aromatic scaffolds: chemistry of diazadiborinines Kinjo, Rei School of Physical and Mathematical Sciences Science::Chemistry Aromaticities Electronic Natures The concept of aromaticity has been of paramount significance in myriad fields of chemistry. To modulate the intrinsic electronic nature of aromatic molecules, partial incorporation of heteroatoms into the benzene scaffold represents a useful strategy in modern inorganic chemistry. This account presents how to incorporate boron into aromatic six‒membered scaffolds, leading to hybrid organic/inorganic benzenes, namely diazadiborinines. In addition, their reactivity towards a variety of substrates are summarized. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University These works were supported by Nanyang Technological University, the Singapore Ministry of Education (MOE2013-T2-1-005, MOE2015-T2-2-032, MOE2018-T2-2-048(S)), and A*Star (Agency for Science, Technology and Research of Singapore (PSF/SERC 1321202066). 2022-09-20T06:37:13Z 2022-09-20T06:37:13Z 2021 Journal Article Kinjo, R. (2021). How to install Boron into aromatic scaffolds: chemistry of diazadiborinines. Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, 79(11), 1056-1064. https://dx.doi.org/10.5059/YUKIGOSEIKYOKAISHI.79.1056 0037-9980 https://hdl.handle.net/10356/161802 10.5059/YUKIGOSEIKYOKAISHI.79.1056 2-s2.0-85119990957 11 79 1056 1064 en MOE2013-T2-1-005 MOE2015-T2-2-032 MOE2018-T2-2-048(S) PSF/SERC 1321202066 Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry © 2021 Society of Synthetic Organic Chemistry. All rights reserved. |
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Science::Chemistry Aromaticities Electronic Natures Kinjo, Rei How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
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The concept of aromaticity has been of paramount significance in myriad fields of chemistry. To modulate the intrinsic electronic nature of aromatic molecules, partial incorporation of heteroatoms into the benzene scaffold represents a useful strategy in modern inorganic chemistry. This account presents how to incorporate boron into aromatic six‒membered scaffolds, leading to hybrid organic/inorganic benzenes, namely diazadiborinines. In addition, their reactivity towards a variety of substrates are summarized. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Kinjo, Rei |
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Kinjo, Rei |
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Kinjo, Rei |
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How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
title_short |
How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
title_full |
How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
title_fullStr |
How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
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How to install Boron into aromatic scaffolds: chemistry of diazadiborinines |
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how to install boron into aromatic scaffolds: chemistry of diazadiborinines |
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2022 |
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https://hdl.handle.net/10356/161802 |
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