Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms
This study investigated the pyrolysis of microalgal-bacterial granular sludge for producing bio-oil and biochar. Results showed that the bio-oil productivity of pyrolyzed MBGS reached 39.5-45.4 wt%, while 23.8-41.2% for the nitrogen-containing bio-oil at the temperature of 673-1073 K. Meanwhile the...
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sg-ntu-dr.10356-1620982022-10-04T05:08:43Z Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms Cui, Baihui Chen, Zhihua Guo, Dabin Liu, Yu School of Civil and Environmental Engineering Nanyang Environment and Water Research Institute Advanced Environmental Biotechnology Centre (AEBC) Engineering::Environmental engineering Pyrolysis Kinetics This study investigated the pyrolysis of microalgal-bacterial granular sludge for producing bio-oil and biochar. Results showed that the bio-oil productivity of pyrolyzed MBGS reached 39.5-45.4 wt%, while 23.8-41.2% for the nitrogen-containing bio-oil at the temperature of 673-1073 K. Meanwhile the biochar with a nitrogen content of 3.7-7.0 wt% could also be produced. Moreover, the Van-Krevelen diagram revealed that produced bio-oil had a H/C ratio higher than that from agroforestry biomass, but its O/C ratio was found to be similar to those of coal and biochar. It further appeared from a mass conservation analysis that the highest bio-oil production yield was achieved at a pyrolysis temperature of 773 K, while the pyrolytic kinetics of MBGS in the temperature range studied was governed by the 3-D diffusion mechanism with the activation energy of 224.96 kJ·mol-1. 2022-10-04T05:08:43Z 2022-10-04T05:08:43Z 2022 Journal Article Cui, B., Chen, Z., Guo, D. & Liu, Y. (2022). Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms. Bioresource Technology, 349, 126328-. https://dx.doi.org/10.1016/j.biortech.2021.126328 0960-8524 https://hdl.handle.net/10356/162098 10.1016/j.biortech.2021.126328 34780909 2-s2.0-85124612627 349 126328 en Bioresource Technology © 2021 Published by Elsevier Ltd. All rights reserved. |
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Engineering::Environmental engineering Pyrolysis Kinetics Cui, Baihui Chen, Zhihua Guo, Dabin Liu, Yu Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
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This study investigated the pyrolysis of microalgal-bacterial granular sludge for producing bio-oil and biochar. Results showed that the bio-oil productivity of pyrolyzed MBGS reached 39.5-45.4 wt%, while 23.8-41.2% for the nitrogen-containing bio-oil at the temperature of 673-1073 K. Meanwhile the biochar with a nitrogen content of 3.7-7.0 wt% could also be produced. Moreover, the Van-Krevelen diagram revealed that produced bio-oil had a H/C ratio higher than that from agroforestry biomass, but its O/C ratio was found to be similar to those of coal and biochar. It further appeared from a mass conservation analysis that the highest bio-oil production yield was achieved at a pyrolysis temperature of 773 K, while the pyrolytic kinetics of MBGS in the temperature range studied was governed by the 3-D diffusion mechanism with the activation energy of 224.96 kJ·mol-1. |
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School of Civil and Environmental Engineering |
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School of Civil and Environmental Engineering Cui, Baihui Chen, Zhihua Guo, Dabin Liu, Yu |
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Article |
author |
Cui, Baihui Chen, Zhihua Guo, Dabin Liu, Yu |
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Cui, Baihui |
title |
Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
title_short |
Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
title_full |
Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
title_fullStr |
Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
title_full_unstemmed |
Investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
title_sort |
investigations on the pyrolysis of microalgal-bacterial granular sludge: products, kinetics, and potential mechanisms |
publishDate |
2022 |
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https://hdl.handle.net/10356/162098 |
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1746219678432231424 |