Pillararene-based self-assemblies for electrochemical biosensors
The ingenious design and synthesis of novel macrocycles bring out renewed vigor of supramolecular chemistry in the past decade. As an intriguing class of macrocycles, pillararene and pillararene-based functional materials that are constructed through the noncovalent bond self-assembly approach have...
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sg-ntu-dr.10356-1623382022-10-14T07:35:38Z Pillararene-based self-assemblies for electrochemical biosensors Cao, Shuai Zhou, Le Liu, Chang Zhang, Huacheng Zhao, Yuxin Zhao, Yanli School of Physical and Mathematical Sciences Science::Chemistry Self-Assembly Supramolecular Chemistry The ingenious design and synthesis of novel macrocycles bring out renewed vigor of supramolecular chemistry in the past decade. As an intriguing class of macrocycles, pillararene and pillararene-based functional materials that are constructed through the noncovalent bond self-assembly approach have been undergoing a rapid growth, benefiting from their unique structures and physiochemical properties. This review elaborates recent significant advances of electrochemical studies based on pillararene systems. Fundamental electrochemical behavior of pillar[n]arene[m]quinone and pillararene-based self-assemblies as well as their applications in electrochemical biosensors are highlighted. In addition, the advantages and functions of pillararene self-assembly systems resulted from the unique molecular architectures are analyzed. Finally, current challenges and future development tendency in this burgeoning field are discussed from the viewpoint of both fundamental research and applications. Overall, this review not only manifests the main development vein of pillararene-based electrochemical systems, but also conquers a solid foundation for their further bioelectrochemical applications. National Research Foundation (NRF) The authors acknowledge the financial support from the “Young Talent Support Plan” (No. 0107–71211510706, 0107–7121191202, 0001–7121191207, and 050700–71240000000046) of Xi’an Jiaotong University, the National Natural Science Foundation of China (No. 62074123 and 61701543), and the PetroChina Innovation Foundation (No. 2019D-5007-0410). This research is also supported by the Singapore National Research Foundation Investigatorship (No. NRFNRFI2018-03) and the Singapore Academic Research Fund (No. TR12/ 19). 2022-10-14T07:35:38Z 2022-10-14T07:35:38Z 2021 Journal Article Cao, S., Zhou, L., Liu, C., Zhang, H., Zhao, Y. & Zhao, Y. (2021). Pillararene-based self-assemblies for electrochemical biosensors. Biosensors and Bioelectronics, 181, 113164-. https://dx.doi.org/10.1016/j.bios.2021.113164 0956-5663 https://hdl.handle.net/10356/162338 10.1016/j.bios.2021.113164 33744670 2-s2.0-85102621656 181 113164 en NRF-NRFI2018-03 TR12/19 Biosensors and Bioelectronics © 2021 Elsevier B.V. All rights reserved |
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Science::Chemistry Self-Assembly Supramolecular Chemistry Cao, Shuai Zhou, Le Liu, Chang Zhang, Huacheng Zhao, Yuxin Zhao, Yanli Pillararene-based self-assemblies for electrochemical biosensors |
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The ingenious design and synthesis of novel macrocycles bring out renewed vigor of supramolecular chemistry in the past decade. As an intriguing class of macrocycles, pillararene and pillararene-based functional materials that are constructed through the noncovalent bond self-assembly approach have been undergoing a rapid growth, benefiting from their unique structures and physiochemical properties. This review elaborates recent significant advances of electrochemical studies based on pillararene systems. Fundamental electrochemical behavior of pillar[n]arene[m]quinone and pillararene-based self-assemblies as well as their applications in electrochemical biosensors are highlighted. In addition, the advantages and functions of pillararene self-assembly systems resulted from the unique molecular architectures are analyzed. Finally, current challenges and future development tendency in this burgeoning field are discussed from the viewpoint of both fundamental research and applications. Overall, this review not only manifests the main development vein of pillararene-based electrochemical systems, but also conquers a solid foundation for their further bioelectrochemical applications. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Cao, Shuai Zhou, Le Liu, Chang Zhang, Huacheng Zhao, Yuxin Zhao, Yanli |
format |
Article |
author |
Cao, Shuai Zhou, Le Liu, Chang Zhang, Huacheng Zhao, Yuxin Zhao, Yanli |
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Cao, Shuai |
title |
Pillararene-based self-assemblies for electrochemical biosensors |
title_short |
Pillararene-based self-assemblies for electrochemical biosensors |
title_full |
Pillararene-based self-assemblies for electrochemical biosensors |
title_fullStr |
Pillararene-based self-assemblies for electrochemical biosensors |
title_full_unstemmed |
Pillararene-based self-assemblies for electrochemical biosensors |
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pillararene-based self-assemblies for electrochemical biosensors |
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2022 |
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https://hdl.handle.net/10356/162338 |
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1749179170144911360 |