An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole
Regioselective Huisgen cycloaddition reaction between 1,2-diboraallene and azide proceeds under catalyst-free and mild conditions to furnish a diboratriazole (2). X-ray diffraction analysis and computational studies confirmed the delocalization of π electrons over the B2 N3 five-membered ring of (2)...
محفوظ في:
| المؤلفون الرئيسيون: | , |
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| مؤلفون آخرون: | |
| التنسيق: | مقال |
| اللغة: | English |
| منشور في: |
2022
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| الموضوعات: | |
| الوصول للمادة أونلاين: | https://hdl.handle.net/10356/162733 |
| الوسوم: |
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| المؤسسة: | Nanyang Technological University |
| اللغة: | English |
| الملخص: | Regioselective Huisgen cycloaddition reaction between 1,2-diboraallene and azide proceeds under catalyst-free and mild conditions to furnish a diboratriazole (2). X-ray diffraction analysis and computational studies confirmed the delocalization of π electrons over the B2 N3 five-membered ring of (2), indicating its aromatic features. Molecule (2) spontaneously releases N2 to form the 2,3-dibora-4-aza-1,3-butenyne derivative (3). The mechanism of a whole reaction profile was extensively investigated by density functional theory (DFT) calculations. |
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