An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole

• Main Authors: Zhu, Lizhao, Kinjo, Rei
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2022
• Subjects: Science::Chemistry; Aromaticity; Huisgen Reaction
• Online Access: https://hdl.handle.net/10356/162733
• Institution: Nanyang Technological University

Regioselective Huisgen cycloaddition reaction between 1,2-diboraallene and azide proceeds under catalyst-free and mild conditions to furnish a diboratriazole (2). X-ray diffraction analysis and computational studies confirmed the delocalization of π electrons over the B2 N3 five-membered ring of (2)...