An inorganic Huisgen reaction between a 1,2-diboraallene and an azide to access a diboratriazole

• المؤلفون الرئيسيون: Zhu, Lizhao, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Aromaticity; Huisgen Reaction
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/162733

Regioselective Huisgen cycloaddition reaction between 1,2-diboraallene and azide proceeds under catalyst-free and mild conditions to furnish a diboratriazole (2). X-ray diffraction analysis and computational studies confirmed the delocalization of π electrons over the B2 N3 five-membered ring of (2)...