Observation of optical gain from aqueous quantum well heterostructures in water
Although achieving optical gain using aqueous solutions of colloidal nanocrystals as a gain medium is exceptionally beneficial for bio-optoelectronic applications, the realization of optical gain in an aqueous medium using solution-processed nanocrystals has been extremely challenging because of th...
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Main Authors: | , , , , , , , , |
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Format: | Article |
Language: | English |
Published: |
2023
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/165210 |
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Institution: | Nanyang Technological University |
Language: | English |
Summary: | Although achieving optical gain using aqueous solutions of colloidal nanocrystals as a gain medium is exceptionally beneficial for bio-optoelectronic applications, the realization of optical gain in
an aqueous medium using solution-processed nanocrystals has been extremely challenging because of the need for surface modification to make nanocrystals water dispersible while still
maintaining their gain. Here, we present the achievement of optical gain in an aqueous medium using an advanced architecture of CdSe/CdS@CdxZn1−xS core/crown@gradient-alloyed shell colloidal quantum wells (CQWs) with an ultralow threshold of ∼3.4 µJ cm−2 and an ultralong gain lifetime of ∼2.6 ns. This demonstration of optical gain in an aqueous medium is a result of the carefully
heterostructured CQWs having large absorption cross-section and gain cross-section in addition to inherently slow Auger recombination in these CQWs. Furthermore, we show low-threshold in-water
amplified spontaneous emission (ASE) from these aqueous CQWs with a threshold of 120 µJ cm−2
In addition, we demonstrate a whispering gallery mode laser with a low threshold of ∼30 µJ
cm−2 obtained by incorporating films of CQWs by exploiting layerby-layer approach on a fiber. The observation of low-threshold optical gain with ultralong gain lifetime presents a significant step
toward the realization of advanced optofluidic colloidal lasers and their continuous-wave pumping. |
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