Synthesis and application of novel bonded cationic β-cyclodextrin derivatives as chiral stationary phases for supercritical fluid chromatography

• Main Author: Liu, Maolong.
• Other Authors: Ng Siu Choon
• Format: Final Year Project
• Language: English
• Published: 2009
• Subjects: DRNTU::Science::Chemistry::Analytical chemistry::Chromatography
• Online Access: http://hdl.handle.net/10356/16714
• Institution: Nanyang Technological University

A novel cationic β-cyclodextrin derivative named mono-6A-(3-vinylimidazolium)-6A-deoxyperphenylcarbamoylated-β-cyclodextrin chloride was synthesized by selective tosylation and vinylimidazole substitution followed by perfunctionalisation with phenylcarbamate groups. The fully derivatized β-cyclodext...