Efficient generation of emissive many-body correlations in copper-doped colloidal quantum wells

• Main Authors: Yu, Junhong, Sharma, Manoj, Li, Mingjie, Liu, Baiquan, Hernández-Martínez, Pedro Ludwig, Delikanli, Savas, Sharma, Ashma, Altintas, Yemliha, Hettiarachchi, Chathuranga, Sum, Tze Chien, Demir, Hilmi Volkan, Dang, Cuong
• Other Authors: School of Electrical and Electronic Engineering
• Format: Article
• Language: English
• Published: 2023
• Subjects: Engineering::Electrical and electronic engineering; Colloidal Quantum Wells; High-Order Excitonic States
• Online Access: https://hdl.handle.net/10356/168692
• Institution: Nanyang Technological University

Colloidal quantum wells (CQWs) provide an appealing platform to achieve emissive many-body correlations for novel optoelectronic devices, given that they act as hosts for strong carrier Coulomb interactions and present suppressed Auger recombination. However, the demonstrated high-order excitonic emission in CQWs requires ultrafast pumping with high excitation levels and can only be spectrally resolved at the single-particle level under cryogenic conditions. Here, through systematic investigation using static power-dependent emission spectroscopy and transient carrier dynamics, we show that Cu-doped CdSe CQWs exhibit continuous-wave-pumped high-order excitonic emission at room temperature with a large binding energy of ∼64 meV. We attribute this unique behavior to dopant excitons in which the ultralong lifetime and the highly localized wavefunction facilitate the formation of many-body correlations. The spectrally resolved high-order excitonic emission generated at power levels compatible with solar irradiation and electrical injection might pave the way for novel solution-processed solid-state devices.