Aqueous C–H aminomethylation of phenols by iodine catalysis
A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage funct...
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2023
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sg-ntu-dr.10356-1701952023-08-31T03:12:21Z Aqueous C–H aminomethylation of phenols by iodine catalysis Zhou, Zhi-Hua Wang, Ben Ding, Yao Loh, Teck-Peng Tian, Jie-Sheng School of Chemistry, Chemical Engineering and Biotechnology Engineering::Chemical engineering Catalysis Iodine A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage functionalization of ten functional molecules that contain phenolic structures. Ministry of Education (MOE) This work was supported by Northwestern Polytechnical University, the Fundamental Research Funds for the Central Universities (D5000210701, D5000210703), and AcRF Tier 1 grants from the Ministry of Education of Singapore (RG11/20 and RT14/20). 2023-08-31T03:12:20Z 2023-08-31T03:12:20Z 2023 Journal Article Zhou, Z., Wang, B., Ding, Y., Loh, T. & Tian, J. (2023). Aqueous C–H aminomethylation of phenols by iodine catalysis. Chemical Communications, 59(2), 223-226. https://dx.doi.org/10.1039/D2CC05746H 1359-7345 https://hdl.handle.net/10356/170195 10.1039/D2CC05746H 2 59 223 226 en RG11/20 RT14/20 Chemical Communications © 2023 The Royal Society of Chemistry. All rights reserved. |
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Engineering::Chemical engineering Catalysis Iodine |
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Engineering::Chemical engineering Catalysis Iodine Zhou, Zhi-Hua Wang, Ben Ding, Yao Loh, Teck-Peng Tian, Jie-Sheng Aqueous C–H aminomethylation of phenols by iodine catalysis |
| description |
A transition-metal-free strategy regarding an iodine-sodium percarbonate catalysis to achieve the ortho-aminomethylation of phenols in aqueous media has been developed. This method can effectively broaden a wide range of phenols, tolerate sensitive functional groups, and achieve the late-stage functionalization of ten functional molecules that contain phenolic structures. |
| author2 |
School of Chemistry, Chemical Engineering and Biotechnology |
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School of Chemistry, Chemical Engineering and Biotechnology Zhou, Zhi-Hua Wang, Ben Ding, Yao Loh, Teck-Peng Tian, Jie-Sheng |
| format |
Article |
| author |
Zhou, Zhi-Hua Wang, Ben Ding, Yao Loh, Teck-Peng Tian, Jie-Sheng |
| author_sort |
Zhou, Zhi-Hua |
| title |
Aqueous C–H aminomethylation of phenols by iodine catalysis |
| title_short |
Aqueous C–H aminomethylation of phenols by iodine catalysis |
| title_full |
Aqueous C–H aminomethylation of phenols by iodine catalysis |
| title_fullStr |
Aqueous C–H aminomethylation of phenols by iodine catalysis |
| title_full_unstemmed |
Aqueous C–H aminomethylation of phenols by iodine catalysis |
| title_sort |
aqueous c–h aminomethylation of phenols by iodine catalysis |
| publishDate |
2023 |
| url |
https://hdl.handle.net/10356/170195 |
| _version_ |
1779156328256634880 |