A mixed Cd/Cu-based metal-organic framework achieved by postsynthetic metal exchange for electrocatalytic oxidation of uric acid

• Main Authors: Ma, Yun-Xiang, Liu, Chang, Ma, Jian-Fang, Zhao, Yanli
• Other Authors: School of Chemistry, Chemical Engineering and Biotechnology
• Format: Article
• Language: English
• Published: 2023
• Subjects: Engineering::Chemical engineering; Carboxylate Ions; Dimethylforamide
• Online Access: https://hdl.handle.net/10356/170416
• Institution: Nanyang Technological University

In this work, we designed a Cd/macrocycle-based metal-organic framework (MOF), namely, [Cd5O(L)(H2O)4]4DMF·5H2O (Cd-L) (L8-= calix[4]resorcinarene-based carboxylate ion and DMF = N,N-dimethylforamide). The pentanuclear Cd-O clusters are linked by L8-anions to form a polymeric structure. Eight coordi...