Reactivity of cyclic (alkyl)(amino)germylene towards copper(I) and gold(I) complexes

• Main Authors: Feng, Zhongtao, Wang, Liliang, Sharifah Nadhirah Binte Shaik Mohammed, Rao, Bin, Kinjo, Rei
• 其他作者: School of Chemistry, Chemical Engineering and Biotechnology
• 格式: Article
• 語言: English
• 出版: 2023
• 主題: Science::Chemistry; Germylene; Copper
• 在線閱讀: https://hdl.handle.net/10356/171088
• 機構: Nanyang Technological University

The reactions of cyclic (alkyl)(amino)germylenes (CAAGe) with copper(I) and gold(I) complexes were investigated. CAAGe (1) reacts with CuBr(SMe2 ) leading to a tetrameric germylene complex [CAAGeCuBr]4 (2), whereas CAAGe (3) undergoes Au-Cl bond insertion with LAuCl (L=phosphine or N-heterocyclic ca...