A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles

A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles

Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-cata...

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Main Authors: Zhang, Ting, Lv, Yongheng, Zhang, Zhenguo, Jia, Zhenhua, Loh, Teck-Peng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Lanthanide
Praseodymium
Online Access:https://hdl.handle.net/10356/171403
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1714032023-11-06T15:34:55Z A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles Zhang, Ting Lv, Yongheng Zhang, Zhenguo Jia, Zhenhua Loh, Teck-Peng School of Physical and Mathematical Sciences Science::Chemistry Lanthanide Praseodymium Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope. Agency for Science, Technology and Research (A*STAR) Ministry of Education (MOE) Nanyang Technological University Submitted/Accepted version We thank the financial support from the Start-up Grant of Nanjing Tech University (Nos. 38274017103, 38037037). T.-P.L. thanks the financial support from Distinguished University Professor grant (Nanyang Technological University), AcRF Tier 1 grants from the Ministry of Education of Singapore (RG 107/19, RG 11/20 and RT 14/20), and the Agency for Science, Technology and Research (A*STAR) under its MTC Individual Research Grants (M21K2c0114). 2023-10-24T03:23:25Z 2023-10-24T03:23:25Z 2023 Journal Article Zhang, T., Lv, Y., Zhang, Z., Jia, Z. & Loh, T. (2023). A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles. Organic Letters, 25(24), 4468-4472. https://dx.doi.org/10.1021/acs.orglett.3c01449 1523-7060 https://hdl.handle.net/10356/171403 10.1021/acs.orglett.3c01449 37294030 2-s2.0-85163559125 24 25 4468 4472 en RG 107/19 RG 11/20 RT 14/20 M21K2c0114 Organic Letters © 2023 American Chemical Society. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1021/acs.orglett.3c01449. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Lanthanide
Praseodymium
spellingShingle Science::Chemistry
Lanthanide
Praseodymium
Zhang, Ting
Lv, Yongheng
Zhang, Zhenguo
Jia, Zhenhua
Loh, Teck-Peng
A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
description Rare earth metals exhibit high catalytic activity and selectivity in various organic reactions due to their unique electronic properties. Among them, praseodymium has shown high catalytic activity under mild reaction conditions compared with transitional metals. Here, we report a strategy of Pr-catalyzed aerobic dehydrogenative aromatization of saturated N-heterocycles to produce 7 classes of products with a broad substrate scope.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Zhang, Ting
Lv, Yongheng
Zhang, Zhenguo
Jia, Zhenhua
Loh, Teck-Peng
format Article
author Zhang, Ting
Lv, Yongheng
Zhang, Zhenguo
Jia, Zhenhua
Loh, Teck-Peng
author_sort Zhang, Ting
title A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
title_short A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
title_full A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
title_fullStr A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
title_full_unstemmed A rare earth metal catalyzed aerobic dehydrogenation of N-heterocycles
title_sort rare earth metal catalyzed aerobic dehydrogenation of n-heterocycles
publishDate 2023
url https://hdl.handle.net/10356/171403
_version_ 1783955510453600256

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