Crystalline 2π aromatic azadiboriridinylium: a BN analogue of cyclopropenylium cation

• المؤلفون الرئيسيون: Zhu, Lizhao, Kinjo, Rei
• مؤلفون آخرون: School of Chemistry, Chemical Engineering and Biotechnology
• التنسيق: مقال
• اللغة: English
• منشور في: 2024
• الموضوعات: Aromatic; Cation
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/173359

N-Substitution of a thermally unstable diboratriazole 1 with a trimethylsilyl group affords a remarkably stable diboratriazole derivative 2. Ring contraction of 2 with an N-heterocyclic carbene accompanied by the release of N2 as well as 1,4-hydrogen shift affords a carbene-stabilized azadiboriridin...