Contracted description of driven degenerate multilevel quantum systems
We formulate a contraction theorem that maps quantum dynamics of a multilevel degenerate system (DS) driven by a time-dependent external field to the dynamics of the corresponding contracted non-degenerate system (CNS) of lower dimension, provided transitions between each pair of degenerate levels i...
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sg-ntu-dr.10356-1737782024-03-01T15:46:21Z Contracted description of driven degenerate multilevel quantum systems Xu, Xiangyu Sun, Kewei Gelin, Maxim F. Zhao, Yang School of Materials Science and Engineering Engineering Degenerate levels External fields We formulate a contraction theorem that maps quantum dynamics of a multilevel degenerate system (DS) driven by a time-dependent external field to the dynamics of the corresponding contracted non-degenerate system (CNS) of lower dimension, provided transitions between each pair of degenerate levels in the DS have identical transition dipole moments. The theorem is valid for an external field of any strength and shape, with and without rotating wave approximation in the system-field interaction. It establishes explicit relations between DS and CNS observables, significantly simplifies numerical calculations, and clarifies physical origins of the field-induced DS dynamics. Ministry of Education (MOE) Published version Support from the Singapore Ministry of Education Academic Research Fund Tier 1 (Grant No. RG87/20) is gratefully acknowledged. K.S. and M.F.G. acknowledge support from Hangzhou Dianzi University through startup funding. 2024-02-27T02:08:49Z 2024-02-27T02:08:49Z 2023 Journal Article Xu, X., Sun, K., Gelin, M. F. & Zhao, Y. (2023). Contracted description of driven degenerate multilevel quantum systems. Journal of Chemical Physics, 159(22). https://dx.doi.org/10.1063/5.0178460 0021-9606 https://hdl.handle.net/10356/173778 10.1063/5.0178460 38088431 2-s2.0-85179648937 22 159 en RG87/20 Journal of Chemical Physics © 2023 Author(s). Published under an exclusive license by AIP Publishing. All rights reserved. This article may be downloaded for personal use only. Any other use requires prior permission of the copyright holder. The Version of Record is available online at http://doi.org/10.1063/5.0178460 application/pdf |
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Engineering Degenerate levels External fields Xu, Xiangyu Sun, Kewei Gelin, Maxim F. Zhao, Yang Contracted description of driven degenerate multilevel quantum systems |
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We formulate a contraction theorem that maps quantum dynamics of a multilevel degenerate system (DS) driven by a time-dependent external field to the dynamics of the corresponding contracted non-degenerate system (CNS) of lower dimension, provided transitions between each pair of degenerate levels in the DS have identical transition dipole moments. The theorem is valid for an external field of any strength and shape, with and without rotating wave approximation in the system-field interaction. It establishes explicit relations between DS and CNS observables, significantly simplifies numerical calculations, and clarifies physical origins of the field-induced DS dynamics. |
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School of Materials Science and Engineering |
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School of Materials Science and Engineering Xu, Xiangyu Sun, Kewei Gelin, Maxim F. Zhao, Yang |
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Article |
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Xu, Xiangyu Sun, Kewei Gelin, Maxim F. Zhao, Yang |
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Xu, Xiangyu |
title |
Contracted description of driven degenerate multilevel quantum systems |
title_short |
Contracted description of driven degenerate multilevel quantum systems |
title_full |
Contracted description of driven degenerate multilevel quantum systems |
title_fullStr |
Contracted description of driven degenerate multilevel quantum systems |
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Contracted description of driven degenerate multilevel quantum systems |
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contracted description of driven degenerate multilevel quantum systems |
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2024 |
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https://hdl.handle.net/10356/173778 |
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